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The oxidation of unsymmetrical thiolsufinate : evidence for α-disulfoxide as an intermediate

✍ Scribed by S. Oae; Y.H. Kim; T. Takata; D. Fukushima


Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
231 KB
Volume
18
Category
Article
ISSN
0040-4039

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✍ W.J.M. van Tilborg; J.R. van der Vecht; H. Steinberg; Th.J. de Boer 📂 Article 📅 1972 🏛 Elsevier Science 🌐 French ⚖ 170 KB

AS part of our interest in cyclopropyl compounds with an exocyclic double bond, we have investigated the quaternary ammonium salt 1, l-(o-hydroxyphenyl)cyclo-propyltrimethylammoniumiodide2 under alkaline conditions, normally favouring Hofmann elimination. Heating of 1 with 3.5 eq. of KOH for 36 hrs