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Evidence for cyclohexyne as an intermediate in the coupling of phenyllithium with 1-chlorocyclohexene

✍ Scribed by F. Scardiglia; John D. Roberts

Publisher
Elsevier Science
Year
1957
Tongue
French
Weight
143 KB
Volume
1
Category
Article
ISSN
0040-4020

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πŸ“œ SIMILAR VOLUMES

Evidence for a diradical intermediate in
Evidence for a diradical intermediate in the Diels–Alder reaction of 2-butene with cyclohexa-1,3-diene
✍ G. Huybrechts; B. Van Mele πŸ“‚ Article πŸ“… 1978 πŸ› John Wiley and Sons 🌐 English βš– 254 KB

Despite an extensive literature, controversy about the Diels-Alder reaction mechanism still exists. For the thermal dimerization of 1,3-butadiene, for example, a concerted one-step [I] or two-stage [2] mechanism, a mixture of orbital symmetry allowed and forbidden cycloadditions 131, as well as a tw