The oxidation of thallium(I) by alkaline ferricyanide
โ Scribed by G.S. Deshmukh
- Publisher
- Elsevier Science
- Year
- 1955
- Tongue
- English
- Weight
- 255 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0003-2670
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The complementary reaction between T1 t and AuC12 was studied in a 3.0 mol dm-3 HC1 medium. The active species of oxidant and reductant were found to be HAuCI+ and T1C12, respectively. A mechanism involving these reactive species is proposed, in agreement with the results obtained.
The hexacyanoferrate(II1)-thallium(1) reaction in aqueous acetic acid containing large concentrations of hydrochloric acid is considerably accelerated both by hydrogen and chloride ions as well as increasing acetic acid in the medium. The experimental results obey the rate law (1) where PI to p6 (1
A method for the direct potentiometric oxidation titration of aqueous phase humic substances with potassium ferricyanide (K,Fe(C!N),) has been developed. Oxidative titrations of humic acid were carried out at varying analyte concentrations, and at values of pH ranging from 5.0 to 11.0. Model synthet