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The Oxidation of Tetramethyl-1,3-bis-(p-tolyl)-disiloxane to 1,3-Bis-(p-carboxyphenyl)-tetramethyldisiloxane

✍ Scribed by Lewis, Daniel W.; Gainer, Gordon C.


Book ID
126209803
Publisher
American Chemical Society
Year
1952
Tongue
English
Weight
431 KB
Volume
74
Category
Article
ISSN
0002-7863

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Whereas 3,4-bis(p-dimethylaminophenyl)-1,2-dithiete ( 18) is are suggested as key intermediates. X-ray crystallography of the disulfide 31 obtained from the main product 30 in equilibrium with its ring-opened valence isomer 19/19Ј, which can also exist as a solid, the analogously disubstituted unequ