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Synthesis of titanocene derivatives of tetramethyldisiloxane and poly(methylsiloxane) and the molecular structure of the disiloxane-bridged titanocene dichloride [1,3-bis(.eta.5-cyclopentadienyl)-1,1,3,3,-tetramethyldisiloxane]titanium(IV) dichloride

✍ Scribed by Curtis, M. David; D'Errico, John J.; Duffy, D. Neil; Epstein, Paul S.; Bell, Larry G.


Book ID
126946382
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
881 KB
Volume
2
Category
Article
ISSN
0276-7333

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## Abstract The syntheses of a series of l‐methyl‐3‐aryl‐substituted titanocene and zirconocene dichlorides are reported. These complexes are synthesized by the reaction of 2‐ and 3‐methyl‐6, 6‐dimethylfulvenes (1:4) with aryllithium, followed by the reaction with TiCl~4~Β·2THF, ZrCl~4~ and (CpTiCl~