Synthesis and X-ray crystal structure of [1,3-bis(η5-cyclopentadienyl)-1,1,3,3-tetramethyldisiloxane]hafnium(IV) dichloride
✍ Scribed by N. Klouras; N. Tzavellas; C. P. Raptopoulou
- Publisher
- Springer Vienna
- Year
- 1997
- Tongue
- English
- Weight
- 389 KB
- Volume
- 128
- Category
- Article
- ISSN
- 0026-9247
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## Abstract The syntheses of a series of l‐methyl‐3‐aryl‐substituted titanocene and zirconocene dichlorides are reported. These complexes are synthesized by the reaction of 2‐ and 3‐methyl‐6, 6‐dimethylfulvenes (1:4) with aryllithium, followed by the reaction with TiCl~4~·2THF, ZrCl~4~ and (CpTiCl~
Synttbesi of B i s ( ~s ~y l o p o n t 4 d i e y l ~~, 2 3 t r i p b e n y l t n ~~~ yl)zirconium(lV) nod -hnfniam(IV), [(q54Z5H5)2--PPb -PPh)] (M = Zr, HT), and Structure of tbe Hafm e n e Derivative The reaction of [MCp+2l2] (M = Zr, HI; Cp = qS-C5H5) with [LiPHPh . 2 THFI and of [ZrCbMez] with PH