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The oxidation of hydrazine derivatives with 4-phenyl-1,2,4-triazoline-3,5-dione

✍ Scribed by R. Ahmed; J.-P. Anselme

Publisher: Elsevier Science
Year: 1972
Tongue: French
Weight: 535 KB
Volume: 28
Category: Article
ISSN: 0040-4020
DOI: 10.1016/0040-4020(72)88145-6

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## Abstract Relative rates of [4 + 2] cycloadditions of cyclopentadienes 1a–1e with 4‐phenyl‐1,2,4‐triazoline‐3,5‐dione (2) in 12 different solvents vary by factors of up to 19000, but the reactions show similar solvent effects. Rate constants __k__~2~ correlate well with solvent parameters __AN__