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Propellanes—XXXVIII : Reaction of tetraenic thiapropellanes and their derivatives with 4-phenyl-1,2,4-triazoline-3,5-dione

✍ Scribed by J. Kalo; E. Vogel; D. Ginsburg

Publisher: Elsevier Science
Year: 1977
Tongue: French
Weight: 575 KB
Volume: 33
Category: Article
ISSN: 0040-4020
DOI: 10.1016/0040-4020(77)80411-0

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## Abstract Two isomeric propellane epoxides **1a** and **1b** containing a cyclohexadiene ring are attacked by the title dienophile as predicted, __syn__ to the five‐membered ether ring whose α‐hydrogens exert less repulsion than the α‐epoxy hydrogens or the epoxide oxygen, respectively, of the cy