✦ LIBER ✦

The oxidation of CFClCFCl and CF2CCl2

✍ Scribed by Eugenio Sanhueza; Julian Heicklen

Publisher: John Wiley and Sons
Year: 1975
Tongue: English
Weight: 633 KB
Volume: 7
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550070308

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✦ Synopsis

The oxidation of CFClCFCl and CF2CC12 were studied at room temperature by chlorine-

The chlorine-atom initiated oxidation 0 -CFClCFCl yields Its quantum yield is -420, which gives k,,/k,b = and oxygen-atom initiation. CCI,FCF(O) as the exclusive product. 210 where reactions (3a) and ( ) are (3a)

The 0(3P)-CF2CC12 interaction yields CF2O and C m C 1 2 with quantum yields of 1 .O and -0.85, respectively. In the presence of 0 2 the radical chain products are observed, but the mechanism is different than that for other chloroolefins.

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## Abstract Rate coefficients, __k__, and ClO radical product yields, __Y__, for the gas‐phase reaction of O(^1^D) with CClF~2~CCl~2~F (CFC‐113) (__k__~2~), CCl~3~CF~3~ (CFC‐113a) (__k__~3~), CClF~2~CClF~2~ (CFC‐114) (__k__~4~), and CCl~2~FCF~3~ (CFC‐114a) (__k__~5~) at 296 K are reported. Rate coe