Under inert atmosphere, dimethyldioxirane 1 converts benzaldehydes solely to the corresponding acids; the reaction is insensitive to electronic effects; yields are limited by the competing decomposition of 1 to acetol; Q2 trapping of free-radical intermediates is observed. Dioxiranes, three-membered
β¦ LIBER β¦
The oxidation of benzaldehyde
β Scribed by W. P. Jorissen; P. A. A. van der Beek
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 217 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0165-0513
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