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The origin of the inverse isotope effect in the PdH and PdD systems

โœ Scribed by Hua Chen; Fu-sui Liu


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
293 KB
Volume
137
Category
Article
ISSN
0375-9601

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Inverse deuterium isotope effect in the
โœ J.G. Langan; E.V. Sitzmann; K.B. Eisenthal ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 375 KB

The singlet-to-triplet intersystem crossing rate ( kST) of diphenylcarbene (DPC) is found to exhibit an inverse isotope effect in various solvents. An off-resonance coupling model between the initial singlet state and a sparse triplet vibronic manifold accounts for kST showing both an inverse isotop