Rcccikcd 12 h1.1y 1953 The fluorescence rehxntion kinetics from all-tins retinal in polsr nnd non-polar solvents have been investigated as a function of tempcraturc. An activrltion cnegy of ==I kcal/mole has been measured. Our results, in conjunction with pwious picosecond absorption measurcmeuts ma
The origin of fluorescence from trans-trans diphenylbutadiene
โ Scribed by D.J.S. Birch; R.E. Imhof
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 374 KB
- Volume
- 88
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
โฆ Synopsis
l7uoresccnce decay tme and yield of trans--tram chphenylbutachcnc III mcthylcyclohc\ane~~sohc\anc dnd propylcnr: glycol were measured bctwcen -50 and +SO'C. The radnhvc rate parameter IS mdcpcndcnt of solvent and lcmpcnturc, wth P mean value of 8.2 x lo8 s-r. This IS slmllar to trans-shlbcnc but unhkc longer polycncs, and IS consistent will1 emission from IBE nlhcr than the low-lymg 'Ai skwz.
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