Experimental exchanges between plagioclases (synthesized from gels) and aqueous solutions (0.5N 8N) were carried out according to the reaction 2 NaA1Si308 + CaC12 CaA12Si208 + 4 SiO2 + 2NaC1. Distribution coefficients defined by XA. (XN.cl) 2 KD = (XAb)2 X'CaC12 were determined at 700\* C and 1 kba
The ordering behaviour of albite in aqueous solutions at 1 kbar
โ Scribed by R. A. Mason
- Publisher
- Springer
- Year
- 1979
- Tongue
- English
- Weight
- 434 KB
- Volume
- 68
- Category
- Article
- ISSN
- 0010-7999
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โฆ Synopsis
Albite crystallized hydrothermally from gels of Ablo0 and Ab9o (SiO2)1o (wt %) composition changes in degree of A1, Si order with time to reach a steady value. The steady values are influenced by fluid and gel composition as well as temperature. A1bites grown in long experiments in the presence of NaOH and excess SiO 2 are more ordered than albites grown in similar experiments with pure water and excess SiO 2. This 'catalytic' effect declines as temperature is increased above 600 ~ C.'Partially ordered albites heated hydrothermally at 700 ~ and 725 ~ C decrease in degree of order. When heated at 600 ~ , 650 ~ or 675~ the degree of order either increases very slightly, or remains the same depending on the degree of order initially present.
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