The Octant Rule
β Scribed by David A. Lightner
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 22 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Application of the Octant Rulels3 to interpret n-s\* Cotton effects (CE's) of chiral ketones with deuterium perturbers4 has received very little experimental investigation aside from the recent work of Djerassi et al. 4 on chiral (3R)-deuteriocyclopentanone. The latter, despite its conformational mo
CHIROPTICAL Methods have been used to determine the absolute configuration of twistane by two groups of workers. 2'3Y4 Adachi et a1.,2 by application of the octant rule 5 to the positive Cotton effect of the intermediate ketone &J-L, predicted its absolute configuration to be enantiomeric with that