The O+(4S)+N2(X1Σg+)→NO+(X1Σ+)+N(4S) reaction as a source of highly rotationally excited NO+ in the thermosphere
✍ Scribed by J.W Duff; D.R Smith
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 227 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1364-6826
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Previous work by Manaa and Yarkony has characterized the doublet-quartet crossing region for the title reaction. In the present work, the minimum energy pathways for addition of CH(%) to Nz on the doublet surface and for dissociation of HCNN to HCN+N(S) on the quartet surface are characterized using
Branching fractions are determined for the product NO (A 'X+, u= 0,l) and NO( B 'II, v= 0) emissions as a function of v' in the energy transfer reaction N,(A 'Z:, v') tNO(X 211n v"=O) in a rapidly pumped discharge-flow reactor operated at a total 2 pressure of TC 2 Torr at % 295 K. Using the NO( A Z