The O 1s photoelectron spectrum of molecular oxygen revisited
✍ Scribed by Sorensen, S L; Børve, K J; Feifel, R; de Fanis, A; Ueda, K
- Book ID
- 120967002
- Publisher
- Institute of Physics
- Year
- 2008
- Tongue
- English
- Weight
- 200 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0953-4075
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The He1 photoelectron spectrum of the transient rpcciev S,O has been measured and the experimentally determined ionization potentials are compared with the results of CNDO/Z molecular orbital calculations using Koopmans' theorem. The assignments are compared with those previously sivcn for the serie
of tic anomalous intensity ratio of the two peaks arking from nitrogen 1s ionizatíon of nitric oxide is presented. It is found that correlation effccts in both the ground state of NO, and the íonic states 13il, ' fl) of NO+ contriiutc to deviations of this intcnsity ratio from the "frazen orbital" v