The novel product of cathodic reduction of phthalimide anion
✍ Scribed by Andrzej Orzeszko; Jan K. Maurin; Anna Niedźwiecka-Kornaś; Zygmunt Kazimierczuk
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- French
- Weight
- 344 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0040-4020
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✦ Synopsis
Cathodic reduction of phthalimide anion in methanol was studied. The novel product, N-hydroxyrnethyl-3-hydroxyphthalimidine, was found. Full characterization of this new compound was carried out by means of NMR, FT-IR, MS, and X-ray crystallography. The mechanism of electrolytic formation of N-hydroxymethyl-3hydroxyphthalinudine is proposed.
📜 SIMILAR VOLUMES
The reduction at the dme of aand #?-substituted anthraquinones, phenazines and phenazinc N,N' dioxides, and also of pnitrodiphenyls and pnitrostilbenes, to anion-radicals has been studied in aprotic media. The half-wave potentials of the l-electron process are shown to correlate in a linear manner w