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Cathodic reduction of some aromatic compounds to free anion-radicals

✍ Scribed by A.E. Brodsky; L.L. Gordienko; L.S. Degtiarev

Publisher: Elsevier Science
Year: 1968
Tongue: English
Weight: 410 KB
Volume: 13
Category: Article
ISSN: 0013-4686
DOI: 10.1016/0013-4686(68)80038-6

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✦ Synopsis

The reduction at the dme of aand #?-substituted anthraquinones, phenazines and phenazinc N,N' dioxides, and also of pnitrodiphenyls and pnitrostilbenes, to anion-radicals has been studied in aprotic media. The half-wave potentials of the l-electron process are shown to correlate in a linear manner with the energy of the lowest vacant orbital (in Hiickel's approximation) of the reduced substance.

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