✦ LIBER ✦
ChemInform Abstract: Nucleic Acid Related Compounds. Part 95. Elimination of Chlorine (Radical) or Tosylate (Anion) from C2′ of Nucleoside C3′ Free Radicals as Model Reactions Postulated to Occur at the Active Site of Ribonucleotide Reductases.
✍ Scribed by M. J. ROBINS; Z. GUO; S. F. WNUK
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 32 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Nucleic Acid Related Compounds. Part 95. Elimination of Chlorine (Radical) or Tosylate (Anion) from C2' of Nucleoside C3' Free Radicals as Model Reactions Postulated to Occur at the Active Site of Ribonucleotide Reductases. -The first biomimetic models for differentiation between radical and anionic departure of 2'-substituents upon generation of O3'-containing C3'radicals at active sites of ribonucleotide reductases are presented [no yield given for the reaction (IV) → (II)]. -(ROBINS, M.