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The nature of the rate-determining step in the dienone-phenol rearrangement

✍ Scribed by V.P. Vitullo; N. Grossman

Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
137 KB
Volume
11
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

Spiran isolation in the dienone-phenol r
Spiran isolation in the dienone-phenol rearrangement of steroidal p-quinols
✍ Antoni Planas; Jaime TomΓ‘s; Juan-Julio Bonet πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 French βš– 219 KB

The neutral form of the spirocation intermediate in the dienone-phenol rearrangement of a steroidal p-quinol has been isolated, providing a direct prove of the accepted mechanism. Changing acidic conditions, phenolic products were obtained.