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Spiran isolation in the dienone-phenol rearrangement of steroidal p-quinols

✍ Scribed by Antoni Planas; Jaime Tomás; Juan-Julio Bonet


Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
219 KB
Volume
28
Category
Article
ISSN
0040-4039

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✦ Synopsis


The neutral form of the spirocation intermediate in the dienone-phenol rearrangement of a steroidal p-quinol has been isolated, providing a direct prove of the accepted mechanism. Changing acidic conditions, phenolic products were obtained.


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