The reactions of [Pt3R~6(CO),l(p-H)3(p3-H)] (1) with PMe3 and PPh3 have produced the salts [Pt(PR3)3H]-[Pt3R~6(CO)2,(p3-H)(p-H)2]r 5a and 5d, R = Me and Ph in the yields 9% and 22%, respectively. By contrast the reaction of 1 with PPh, in the presence of Me3N0 has yielded the phosphane-substituted d
✦ LIBER ✦
The Nature of the Metal—Silicon Bond in [M(SiR3)H3(PPh3)3] (M = Ru, Os) And the Crystal Structure of [Os{Si(N-pyrrolyl)3}H3(PPh3)3]
✍ Scribed by Dr. Klaus Hübler; Dr. Ute Hübler; Prof. Warren R. Roper; Prof. Peter Schwerdtfeger; Dr. L. James Wright
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 1012 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0947-6539
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