The oxidation of norbornene (la) by chromyl chloride has recently been carried out by Freeman et al. as part of a kinetic study of the mechanism of oxidation by this reagent (1). Unfortunately no product analysis was made. We have repeated this reaction and the products
The nature of the activated complex in the chromyl chloride oxidation of cycloalkenes
β Scribed by Fillmore Freeman; Nira J. Yamachika
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- French
- Weight
- 177 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
The chromyl chloride oxidation of unsaturates has been extensively investigated by a large nmber of workers (1,3-7). In order to account for the variety of products, several intermediates (I-IV) have been proposed. Rowever, these deductions have been drawn from
π SIMILAR VOLUMES
The presence of branches in poly(viny1 chloride) as indicated by previous IR measurements on the polymer reduced to polyethylene by means of lithium aluminum hydridc is believed to affect materially the morphology and solid state properties of poly(viny1 chloride); however, up to the present, the na