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The Nasicon-like copper(II) zirconium phosphate Cu0.5Zr2(PO4)3 and related compounds

โœ Scribed by A. El Jazouli; M. Alami; R. Brochu; J.M. Dance; G. Le Flem; P. Hagenmuller


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
444 KB
Volume
71
Category
Article
ISSN
0022-4596

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The phosphate Cu I 0.5 Mn II 0.25 Zr 2 (PO 4 ) 3 can be obtained at 10003C by exchange reaction in Cu II 0.5 Zr 2 (PO 4 ) 3 . It crystallizes in the rhombohedral system (space group R3 ) with the parameters a h โ€ซุโ€ฌ 8.8352(1) A s and c h โ€ซุโ€ฌ 22.254(5) A s in the equivalent hexagonal cell. The structu

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The optical (energy level scheme) and magnetic properties (paramagnetic susceptibility as a function of the temperature and g values) of the polycrystalline Co 0.5 Ti 2 (PO 4 ) 3 were simultaneously reproduced by use of a crystal field theory involving a set of F k , , free ion, and B k q crystal fi

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Compounds \(\left(M^{\prime}\right)\left(N^{\mathrm{Vv}}\right)_{2}\left(\mathrm{PO}_{4}\right)_{3}(M=\mathrm{Ag}, \mathrm{Cu} ; N=\mathrm{Ge}, \mathrm{Hf}, \mathrm{Sn}, \mathrm{Ti}, \mathrm{Zr})\) have been synthesized using solid-state reactions. Attempts to synthesize \(\mathrm{CuGe}_{2}\left(\ma

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Hydrothermal reaction of Zr(OPr) 4 with H 3 PO 4 in the presence of ethylene diamine and HF yields three crystalline phases; the 1-D [enH 2 ][Zr(HPO 4 ) 3 ], 1, which can grow as needles over 1 mm in length, the 2-D [enH 2 ] 0.5 [Zr(PO 4 )(HPO 4 )], 2, which is found as thin plates, and the previous