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The n → π★ transition of the carbonyl group and polymer stereoregularity

✍ Scribed by W.M. Pasika; R. Brandon


Publisher
Elsevier Science
Year
1965
Tongue
English
Weight
270 KB
Volume
6
Category
Article
ISSN
0032-3861

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The calculation of solvatochromic shifts
✍ Thomas Fox; Notker Rösch 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 447 KB

The solvatochromic shift of the n-n\* transition of acetone in various solvents is studied theoretically within the INDO/S-CI approach. To incorporate the solvent effect a cavity mode is used that allows an arbitrary shape of the cavity surface. The relative shifts between different solvents caused