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The m/z 91 rearrangement ion in the mass spectra of some 1,4-benzodiazepines

โœ Scribed by Floie M. Vane; Wolfgang Benz


Publisher
John Wiley and Sons
Year
1979
Tongue
English
Weight
435 KB
Volume
14
Category
Article
ISSN
1076-5174

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Rearrangement reactions in the positive
โœ K. P. Madhusudanan; Aboo Shoeb ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 231 KB

The positive and negative ion mass spectra of clausmarin A, a naturally occurring tetracyclic conmarin, have been studied. The base peaks in the positive and negative ion spectra correspond to the complementary ions at mlz 143 and mlz 255, respectively, formed by a rearrangement reaction. The fragme