The Mycoticins, Polyene Macrolides from Streptomyces ruber
β Scribed by Wasserman, H. H.; Van Verth, J. E.; McCaustland, D. J.; Borowitz, I. J.; Kamber, B.
- Book ID
- 126057099
- Publisher
- American Chemical Society
- Year
- 1967
- Tongue
- English
- Weight
- 267 KB
- Volume
- 89
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The degradation of prototype members of the skipped-polyol polyene macrolide class, mycoticins A and B, is reported. The characterization of the resultant fragments allows a partial structure determination to be achieved. The polyene macrolides comprise a large class of natural products which displ
The tetraformylal derivative of mycoticin A and B 2 has been prepared in high yield from the natural products 1. 2-D COSY NMR and NOEDS experiments allow assignment of all nonequivalent hydrogens in 2. NOE difference experiments shed light on the relative stereochemistry and conformation of the skip