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The mutual effect of the reactions of an isocyanate with water and an alcohol

✍ Scribed by Yu.V. Aleksandrova; L.D. Krotova; O.G. Tarakanov


Book ID
118965113
Publisher
Elsevier Science
Year
1976
Weight
257 KB
Volume
18
Category
Article
ISSN
0032-3950

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πŸ“œ SIMILAR VOLUMES


Effect of polar aprotic solvents and org
✍ S. Dabi; A. Zilkha πŸ“‚ Article πŸ“… 1980 πŸ› Elsevier Science 🌐 English βš– 310 KB

DMF and DMSO catalyse the reaction of butanol with PhNCO but inhibit that with aliphatic isocyanates, due to formation of an active 1 : 1 charge transfer complex with the aromatic isocyanate. Similarity was found in the mode of catalysis of the urethane reaction with these solvents to that with tert