Study of the reaction of isocyanates with hydroperoxides and alcohols on the basis of an analysis of their electronic structure
โ Scribed by A. O. Litinskii; A. I. Shreibert; L. -M. Z. Balyavichus; A. B. Bolotin
- Book ID
- 112363954
- Publisher
- Springer
- Year
- 1974
- Tongue
- English
- Weight
- 346 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0040-5760
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DMF and DMSO catalyse the reaction of butanol with PhNCO but inhibit that with aliphatic isocyanates, due to formation of an active 1 : 1 charge transfer complex with the aromatic isocyanate. Similarity was found in the mode of catalysis of the urethane reaction with these solvents to that with tert
The surface grafting reactions of a series of isocyanates with hydroxyapatite particles at different temperatures were studied by Infrared spectrophotometry (IR) and thermal gravimetric analysis (TGA). The study results show that both hexamethylene diisocyanate (HMDI) and isocyanatoethyl methacrylat