The molecular structures of O-methylhydroxylamine, N-methylhydroxylamine, N,O-dimethylhydroxylamine and N,N,O-trimethylhydroxylamine in the gas phase, determined by electron diffraction
β Scribed by David W.H. Rankin; Michael R. Todd; Frank G. Riddell; Eric S. Turner
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 907 KB
- Volume
- 71
- Category
- Article
- ISSN
- 0022-2860
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π SIMILAR VOLUMES
The rate of cleavage of ethyl N-[o -(N-methyl-N-hydroxycarbamoyl)benzoyl]carbamate (ENMBC) in the buffer solutions containing N-methylhydroxylamine, acetate + Nmethylhydroxylamine, and phosphate + N-methylhydroxylamine followed an irreversible consecutive reaction path: ENMBC k 1 obs β A k 2 obs β B
Mixtures of N,O, and N,O, have been prepared from measured volumes of NO and 0,. Phase relationships in the system N,O,/N,O,, which depend on the composition of the samples and on the temperature, were studied by the Guinier technique and differential thermal analysis. Single crystals of phases A an
than the C-O bond length of CH O in the gas phase by 0.044 A at the 3 MP2raug-cc-pVDZ level of theory. The structure of the CH S y moiety in