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The molecular structure of the cubanelike compound, [Mo(NC6H4CH3)(.mu.3-S)(S2P(OC2H5)2)]4, and a description of its bonding

✍ Scribed by Edelblut, A. W.; Folting, K.; Huffman, J. C.; Wentworth, R. A. D.


Book ID
126422508
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
641 KB
Volume
103
Category
Article
ISSN
0002-7863

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Reaction of [Mo 3 Y(m-S) 3 (dtp) 4 (H 2 O)] (Y O, S; dtp S 2 P(OC 2 H 5 ) 2 Γ€ ) with HgI 2 gave the novel compound {[Mo 3 S 7 (dtp) 3 ] 4 Β΄I}{(HgI 3 ) 3 } Β΄4 H 2 O (1), which contains a {[Mo 3 S 7 (dtp) 3 ] 4 Β΄I} tetramer and (HgI 3 ) Γ€ . Compound 1 has been characterized by IR, Raman, UV/Vis, and N