✦ LIBER ✦

The molecular mechanism of the poisoning of platinum and rhodium catalyzed ethylene hydrogenation by carbon monoxide

✍ Scribed by Kevin S. Hwang; Minchul Yang; Ji Zhu; Jeff Grunes; Gabor A. Somorjai

Publisher: Elsevier Science
Year: 2003
Tongue: English
Weight: 371 KB
Volume: 204-205
Category: Article
ISSN: 1381-1169
DOI: 10.1016/s1381-1169(03)00332-7

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Hydrogenation of carbons catalyzed by ni

Hydrogenation of carbons catalyzed by nickel, platinum and rhodium

✍ A. Tomita; N. Sato; Y. Tamai 📂 Article 📅 1974 🏛 Elsevier Science 🌐 English ⚖ 621 KB

Catalytic hydrogenation of a carbon was investigated at a constant temperature. The reaction occurred in two stages as observed therlno~ravimetrically. For a nickel-catalyzed reaction at 540°C about a half of active carbon was rapidly gasified to methane and the remaining carbon was gasified at a v

Alternating oligomerization of ethylene

Alternating oligomerization of ethylene and carbon monoxide catalyzed by rhodium carbonyl

✍ Yuji Iwashita; Mitsuru Sakuraba 📂 Article 📅 1971 🏛 Elsevier Science 🌐 French ⚖ 165 KB

Brubaker and his coworkers have reported the free radical-initiated copolymerization of ethylene and carbon monoxide at superatomospheric pressures (1). Reppe and Magin (2) have found the polyketone formation from ethylene and carbon monoxide in the reaction catalyzed by a large amount of nickel cya

Specific rate enhancement by alkylphosph

Specific rate enhancement by alkylphosphines in a homogeneous rhodium complex-catalyzed hydrogenation of carbon monoxide to ethylene glycol

✍ Hiro-O Tanaka; Yoshinori Hara; Eiichi Watanabe; Keisuke Wada; Tekeru Onoda 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 263 KB

Poisoning of the platinum-catalyzed oxid

Poisoning of the platinum-catalyzed oxidation and hydrogenation of graphite by addition of CCl4

✍ R.T.K. Baker; C.R.F. Lund; J.A. Dumesic 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 324 KB

The effect of adsorbed carbon monoxide o

The effect of adsorbed carbon monoxide on hydrogen adsorption and hydrogen evolution on platinum

✍ E.P.M. Leiva; E. Santos; T. Iwasita 📂 Article 📅 1986 🏛 Elsevier Science ⚖ 687 KB

The mechanism of asymmetric hydrogenatio

The mechanism of asymmetric hydrogenations catalyzed by chiral pyrrolidinephosphine-rhodium complexes

✍ Kazuo Achiwa; Yoko Ohga; Yoichi Iitaka; Hazime Saito 📂 Article 📅 1978 🏛 Elsevier Science 🌐 French ⚖ 225 KB

Effective catalytic asymmetric hydrogenations catalyzed by chiral pyrrolidinephosphine-rhodium complexes have been proven to be useful for the preparation of optically active a-amino acids @3-91%)2'3), isoquinoline salsolidine (45%)6) cc-hydroxy esters (78.5%)4'5), R-(-)-pantolactone C80.5-86.7%17'g