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Alternating oligomerization of ethylene and carbon monoxide catalyzed by rhodium carbonyl

✍ Scribed by Yuji Iwashita; Mitsuru Sakuraba

Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
165 KB
Volume
12
Category
Article
ISSN
0040-4039

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✦ Synopsis

Brubaker and his coworkers have reported the free radical-initiated copolymerization of ethylene and carbon monoxide at superatomospheric pressures (1). Reppe and Magin (2) have found the polyketone formation from ethylene and carbon monoxide in the reaction catalyzed by a large amount of nickel cyan0 complex. Now the authors wish to describe the alternating oligomerization of ethylene and carbon monoxide catalyzed by rhodium carbonyl. From the rhodium catalyzed reaction of ethylene with carbon monoxide in acetic acid, water, alcohols or in

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