𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The molecular geometry of pyrazine in the lowest triplet state from PMDR spectroscopy

✍ Scribed by A.A. Gwaiz; M.A. El-Sayed

Book ID
103009994
Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
433 KB
Volume
19
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

The triplet spin sublevel origins of the bands in the phosphorescke of pyrazine in a paradioxane host are assigned using phosphorescence-microwave double resonance techniques. The assignments cannot be interpreted in terms of a Dzh structure for the molecule in the triplet state, and indicate a trip!et state molecule symmetrr Of Czh or lower.

πŸ“œ SIMILAR VOLUMES

PMDR spectroscopy and the geometry of th
PMDR spectroscopy and the geometry of the triplet state
✍ M.A. El-Sayed; M. Leung; C.T. Lin πŸ“‚ Article πŸ“… 1972 πŸ› Elsevier Science 🌐 English βš– 597 KB

It is shown that phosphorescent m~cro~vave double resonance (PRfDR) an detect deviations from Czv, R,h or Dz symmetry. This is carried out by examining the radiative properties of the zero field level which should be\*"dsrk" for molecules with these symmetries. The results show that in rz-hesone sol

Assignment of the lowest triplet state o
Assignment of the lowest triplet state of benzene using phosphorescence-microwave double resonance (PMDR) techniques
✍ A.A. Gwaiz; M.A. El-Sayed; D.S. Tinti πŸ“‚ Article πŸ“… 1971 πŸ› Elsevier Science 🌐 English βš– 322 KB

Phosphorescence-microwave double resonance (PMDR) techniques are wed and the zero-field (zf) origin of the 0,O band of the phosphorescence of benzene-& in benzene-& a.t 1.6% is determined to be the TY level. This is cuns;tent with a 3B1u assignment for a distorted D2h benzene in its triplet state an

Geometry of ammonia molecule in the lowe
Geometry of ammonia molecule in the lowest triplet state estimated theoretically
✍ Danuta Jeziorek; Bronislaw Ε»urawski πŸ“‚ Article πŸ“… 1979 πŸ› John Wiley and Sons 🌐 English βš– 176 KB

## Abstract The geometrical parameters of the ammonia molecule in the lowest‐lying triplet state have been estimated by means of the SCF method and by making an extrapolation to take into account electron correlation effects. The planar configuration has been obtained as the most probable geometric