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The Modular Approach to Acetylenic Phthalocyanines and Phthalocyanine Analogues

✍ Scribed by Rüdiger Faust


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
353 KB
Volume
2001
Category
Article
ISSN
1434-193X

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✍ Raymond Bonnett; Kawulia Okolo 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 93 KB 👁 2 views

An azadibenzoporphyrin (13,17-diethyl-12,18-dimethyl-5-azadibenzo[b,g]porphyrin, 6) is prepared by a 2 × 2 synthesis from a 1-bromobenzopyrromethene precursor by treatment with sodium azide at 140 °C in solvent. Yields depend on solvent, 35% being obtained in quinoline and 84% in DMF. Treatment of 1