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The Mn(acac)3—RCN—CCl4 system as a new efficient reagent for the oxidation of secondary alcohols into ketones

✍ Scribed by R. I. Khusnutdinov; N. A. Schadneva; A. R. Baiguzina; U. M. Dzhemilev

Book ID
110389874
Publisher
Springer
Year
2002
Tongue
English
Weight
264 KB
Volume
51
Category
Article
ISSN
1573-9171

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Diisopropoxyaluminium trifluoroacetate/4
Diisopropoxyaluminium trifluoroacetate/4-nitrobenzaldehyde — a new oppenauer oxidation system for accelerated oxidation of secondary alcohols to the corresponding ketones
✍ Krishnacharya G. Akamanchi; Bapu A. Chaudhari 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 172 KB

A practical, efficient and accelerated oxidation of secondary alcohols to the corresponding ketones has been achieved at rt in high yields by a modified Oppenauer oxidation system using diisopropoxyaluminium trifluoroacetate as catalyst and 4-nitrobenzaldehyde as a hydride acceptor.