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Diisopropoxyaluminium trifluoroacetate/4-nitrobenzaldehyde — a new oppenauer oxidation system for accelerated oxidation of secondary alcohols to the corresponding ketones

✍ Scribed by Krishnacharya G. Akamanchi; Bapu A. Chaudhari

Book ID: 104257946
Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 172 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)01623-7

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✦ Synopsis

A practical, efficient and accelerated oxidation of secondary alcohols to the corresponding ketones has been achieved at rt in high yields by a modified Oppenauer oxidation system using diisopropoxyaluminium trifluoroacetate as catalyst and 4-nitrobenzaldehyde as a hydride acceptor.

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