The millimeter-wave rotational spectra of the two lowest excited degenerate vibrational states Β£ 7 Γ 1 and Β£ 8 Γ 1 of the symmetric top species trichloroacetonitrile, CCl 3 CN, have been recorded and assigned for JΠ Γ 20 up to JΠ Γ 74. The Coriolis constants z 7 Γ 00.695 and z 8 Γ 0.530 have been de
The Millimeter-Wave Spectrum of Dimethylether-D6 in Excited Torsional States
β Scribed by W. Neustock; A. Guarnieri
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 210 KB
- Volume
- 158
- Category
- Article
- ISSN
- 0022-2852
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β¦ Synopsis
The rotational spectrum of dimethylether- (\mathrm{D}{6}) in the first two excited torsional states between 40 and (100 \mathrm{GHz}) has been measured, and the rotational and quartic distortion constants for both states are given. The analysis of the internal rotation gives the potential parameters (V{3}) and (V_{12}^{\prime}) and the angles between the principal axes of inertia and the internal rotation axes. Also, the moment of inertia (I_{\alpha}) of the (\mathrm{CD}_{3})-group has been determined. (c) 1993 Academic Press. Inc.
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