𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The Millimeter-Wave Spectrum of Chlorine Nitrate (ClONO2): The 2ν9 and ν7 Vibrational States

✍ Scribed by Rebecca A.H. Butler; Sieghard Albert; Douglas T. Petkie; Paul Helminger; Frank C. De Lucia

Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
302 KB
Volume
213
Category
Article
ISSN
0022-2852

No coin nor oath required. For personal study only.

✦ Synopsis

Chlorine nitrate is a molecule of interest in atmospheric studies because of its role as a reservoir species, removing both chlorine and nitrogen species from catalytic cycles of ozone destruction. The ground and ν 9 vibrational states have been previously studied in the millimeter and submillimeter spectral regions. We have now recorded and analyzed the next states that are lowest in energy, the coupled 2ν 9 /ν 7 dyad, from 128 through 355 GHz using a fast scan submillimeter spectroscopic technique system.

📜 SIMILAR VOLUMES

High-Resolution IR Spectrum of SCF2 from
High-Resolution IR Spectrum of SCF2 from 1000 to 1400 cm−1: The ν1/ν3 + 2ν5/ν2 + ν3 and ν4/ν2 + ν5 Interacting States
✍ Jean-Marie Flaud; Wolfgang Jerzembeck; Hans Bürger 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 225 KB

The infrared spectrum of SCF 2 was recorded in the 1000 -1400 cm Ϫ1 region with a resolution of 2.5 ϫ 10 Ϫ3 cm Ϫ1 . The rotationally resolved 1 and 4 band systems were studied for the first time, and altogether 11 500 transitions were assigned. Both fundamentals are involved in strong anharmonic (Fe

Microwave Spectroscopy of the Ground, ν1
Microwave Spectroscopy of the Ground, ν18, 2ν18, and ν11Vibrational States of CF3CFH2
✍ V.V. Ilyushin; E.A. Alekseev; S.F. Dyubko; O.I. Baskakov 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 404 KB

The rotational spectra of the ground, 18 , 2 18 , and 11 vibrational states of CF 3 CFH 2 have been investigated in the frequency range 48 -116 GHz with an accuracy of measurement better than 10 kHz. Rotational and centrifugal distortion parameters derived using an S-reduced Watson-type Hamiltonian

Fourier Transform Infrared Spectra of Fo
Fourier Transform Infrared Spectra of Formaldoxime: The ν7, ν9, ν11, ν12, and 2ν12Bands
✍ R.A. Bannai; G. Duxbury; G. Ritchie; S. Klee 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 364 KB

A first full rotational analysis of high-resolution gas-phase spectra of the lowest frequency fundamental bands, n 9 and n 12 , of formaldoxime, CH 2 NOH, has been completed. In addition the weak n 7 fundamental has been analyzed at medium resolution, and the complex structure of the bands in the n

High-Resolution Infrared Study of the ν7
High-Resolution Infrared Study of the ν7, ν8, and ν15 Bands and Millimeter-Wave Investigation of the v8 = 1 State of CF2Cl–CH3
✍ O.I. Baskakov; V.V. Ilyushin; E.A. Alekseev; H. Bürger; G. Pawelke 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 226 KB

High-resolution (⌬ ϭ 2.3 and 2.9 ϫ 10 Ϫ3 cm Ϫ1 ) FTIR spectra of natural and 35 Cl monoisotopic CH 3 CF 2 Cl have been recorded at Ϫ70°C in the 600 -1400 cm Ϫ1 range. The bands 7 , 8 , and 15 have been rotationally analyzed for both isotopic varieties. With the help of predictions based on 8 paramet

High-Resolution Infrared, Microwave, and
High-Resolution Infrared, Microwave, and Submillimeter-Wave Study of FClO2 in the ν2, ν3, ν4, and ν6 Excited States
✍ J.-M. Flaud; H.S.P. Müller; H. Bürger 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 188 KB

A high-resolution analysis of the {ν 2 , ν 3 } and {ν 4 , ν 6 } bands of the two isotopomers of chloryl fluoride F 35 ClO 2 and F 37 ClO 2 has been carried out for the first time using simultaneously infrared spectra recorded around 16 µm and 26 µm with a resolution of ca. 0.003 cm -1 and microwave