The migratory aptitude in the anodic oxidation of β-hydroxycarboxylic acids, and a new synthesis of di-muscone
✍ Scribed by T. Shono; J. Hayashi; H. Omoto; Y. Matsumura
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- French
- Weight
- 222 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
It has well been known that the electrochemical decarboxylation of 6-hydroxycarboxylic acids gives ketones (I and II in eq (1)) by the rearrangement involving the migration of B-alkyl substituent to the developing cationinc
📜 SIMILAR VOLUMES
This paper is dedicated to Prof. Jochanan Blum on the occasion of his 75th birthday.
Sumnary: a-Hydroxycarboxylic acids (I\_) reacted with N-sulfinylanilines (2) to yive the corresponding a-hydroxyanilides (2) in quantitative yields under mild condition: the reaction appears to involve intermolecular catalysis by the carboxylic acid moiety and intramolecular catalysis by the hydroxy
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