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The microwave spectrum, structure, dipole moment, and 14N nuclear quadrupole coupling constant of acetonitrile-N-oxide

โœ Scribed by P.B. Blackburn; R.D. Brown; F.R. Burden; J.G. Crofts; I.R. Gillard

Publisher
Elsevier Science
Year
1970
Tongue
English
Weight
244 KB
Volume
7
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The microwave spectrum of acetonitrile N-oxide shows that the molecule is a symmetric top. The spectrum of the common isotopic species, both 1% species. the 15N and 180 species have been assigned leading to the r, geometry of all heavy atoms. The nitrogen quadrupofe coupling cehstant is found to be 490 IcHz.

Fmtr, the Stark effect the dipole moment is 1.50 x 10 *z3 Cm (4.49 II). The significance of the observed NO bond length and other properties is dicuased in r&&ion to the electranit: structure of this bond.

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