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The Metallation-Elimination Reaction, II. Monocyclic Anions and Polyanions

✍ Scribed by Wilhelm, Dieter ;Clark, Timothy ;Friedl, Thomas ;von Ragué Schleyer, Paul

Book ID
101814769
Publisher
Wiley (John Wiley & Sons)
Year
1983
Tongue
English
Weight
435 KB
Volume
116
Category
Article
ISSN
0009-2940

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✍ Matteo Cusumano; Maria Letizia Di Pietro; Antonino Giannetto; Pasquale Antonio V 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 157 KB

## Abstract [Pd(bipy)(py)~2~](PF~6~)~2~ reacts stepwise with excess thiourea to give [Pd(tu)~4~](PF~6~)~2~. The kinetics of the second step, which refers to the replacement of bipyridyl in [Pd(bipy)(tu)~2~](PF~6~)~2~, have been studied in water and in the presence of calf thymus DNA, sodium polyrib