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The meta-photocycloaddition of cyclopentene to ortho-methylanisole

✍ Scribed by A. W. H. Jans; J. Cornelisse


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
255 KB
Volume
100
Category
Article
ISSN
0165-0513

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✦ Synopsis


Abstract

Photocycloaddition of cyclopentene to ortho‐methylanisole yields two products. The addition takes place at the positions ortho with respect to the methoxy group.


πŸ“œ SIMILAR VOLUMES


The meta-photocyloaddition of cyclopente
✍ A. W. H. Jans; J. J. van Dijk-Knepper; J. Cornelisse πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 154 KB

## Abstract The __meta__‐photocycloaddition of cyclopentene to anisole yields the hitherto unknown 1‐methoxy‐__exo__‐tetracyclo[6.3.0.0^2,11^.0^3,7^ ]undec‐9‐ene together with the __endo__‐isomer in the ratio 1: 9.3.

Photocycloaddition of ethylvinylether an
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Photocycloaddition of ethylvinylether and cyclopentene to 3,5-dimethylanisole yields derivatives of 1-methoxy-2,4-dimethyltricyclo[3.3.0.0 2y8]oct-3-ene in which the substituents at positions 6 and/or 7 are endo.