The mercury/mercuric oxide electrode in high temperature aqueous solutions
β Scribed by B. Case; G. J. Bignold
- Book ID
- 105076420
- Publisher
- Springer
- Year
- 1971
- Tongue
- English
- Weight
- 428 KB
- Volume
- 1
- Category
- Article
- ISSN
- 0021-891X
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π SIMILAR VOLUMES
The oxidation mechanism of 2-mercaptopyridine N-oxide (NOS) is studied in aqueous media. Polarographic, classical and differential pulse, and voltammetic studies were made. The effect of pH, reactant concentration and scan rate on the electrochemical parameters is studied. The results indicate that
## At high ionic strength the ion pair (NrPy:+. nX-) or complex (NiPy,X,), n = 0, 1, 2; X-= Cl-, Br-. SCN-. N;. F-. NO;. CIO; ; is adsorbed at the surface of mercury electrode. Under specified conditions in chloride, bromide, and thiocyanates solutions the electroreduction is preceded by a crystal