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The dropping mercury electrode in aqueous potassium chloride solution

✍ Scribed by G.H. Nancollas; C.A. Vincent


Publisher
Elsevier Science
Year
1965
Tongue
English
Weight
644 KB
Volume
10
Category
Article
ISSN
0013-4686

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## Reduction of Mn \*+ has been studied in aqueous dioxan mixtures at a dropping mercury electrode. The reduction has been found to be quasi-reversible and hence kinetic parameters (K, and a) have been calculated by Gellings' method. The K, values are found to be in the order of 10m3 cm/s. The eff

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The reduction of Mn\*+ has been studied in formamide, dimethyl formamide and acetonitrile Mn2+ gives well defined current/voltage curves in aqueous and non-aqueous media. The kinetic parameters K, and a have been calculated by means of Matsuda's and Gellings' theoretical treatments in water, aqueous