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The Meisenheimer rearrangement in heterocyclic synthesis. II. Synthesis and X-ray crystal structure of a tetrahydro-1H-2,3-benzoxazocine and preparation of a hexahydro-2,3-benzoxazonine

โœ Scribed by Bremner, JB; Browne, EJ; Davies, PE; Raston, CLWAH


Book ID
121478106
Publisher
Commonwealth Scientific and Industrial Research Organisation Publishing
Year
1980
Tongue
English
Weight
606 KB
Volume
33
Category
Article
ISSN
0004-9425

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]pyridines (THPP) upon the reaction with DMAD in acetonitrile or DMSO at rt underwent ring expansion, affording tetrahydropyrrolo[2,3-d]azocines; these latter compounds have not previously been reported in the literature. The crystal structure and conformation of these derivatives was established by