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The Mechanism of the Self-Initiated Thermal Polymerization of Styrene. Theoretical Solution of a Classic Problem

โœ Scribed by Khuong, Kelli S.; Jones, Walter H.; Pryor, William A.; Houk, K. N.


Book ID
118143892
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
896 KB
Volume
127
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES


The measurement of rates of initiation i
โœ N.J. Barr; W.I. Bengough; G. Beveridge; G.B. Park ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 398 KB

The thermal initiation of the polymerization of styrene has been studied at temperatures from 60-140ยฐC using DPPH as a free radical scavenger. Rates of free radical formation, measured by the decrease in absorbance at 525 nm, are about seven times greater than those obtained from inhibition period m

Radical polymerization of styrene initia
โœ Ramiro Guerrero Santos; Philippe R. Chaumont; Jean E. Herz; Gerard J. Beinert ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 716 KB

A~tract--The present paper reports an investigation on the "pseudo-living'" radical chain propagation process in the case of the styrene polymerization initiated by benzopinacolates. Two steps were observed, as in earlier reported investigations. Oligomers were formed first at low monomer conversion