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Confirmation of the Mayo mechanism for the initiation of the thermal polymerization of styrene

โœ Scribed by Chong, Yen K.; Rizzardo, Ezio; Solomon, David H.


Book ID
125854070
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
266 KB
Volume
105
Category
Article
ISSN
0002-7863

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The measurement of rates of initiation i
โœ N.J. Barr; W.I. Bengough; G. Beveridge; G.B. Park ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 398 KB

The thermal initiation of the polymerization of styrene has been studied at temperatures from 60-140ยฐC using DPPH as a free radical scavenger. Rates of free radical formation, measured by the decrease in absorbance at 525 nm, are about seven times greater than those obtained from inhibition period m