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The mechanism of the oxidative addition of aryl halides to Pd-catalysts: a DFT investigation

✍ Scribed by Goo�en, Lukas J.; Koley, Debasis; Hermann, Holger; Thiel, Walter

Book ID
120175287
Publisher
Royal Society of Chemistry
Year
2004
Tongue
English
Weight
408 KB
Volume
19
Category
Article
ISSN
1359-7345

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Mechanism of the oxidative addition of a
Mechanism of the oxidative addition of aryl halides to bis-carbene palladium(0) complexes
✍ Jutand, Anny (author);Pytkowicz, Julien (author);Roland, Sylvain (author);Mangen 📂 Article 📅 2010 🏛 Walter de Gruyter GmbH 🌐 English ⚖ 400 KB

Bis-__N__-heterocyclic carbenes Pd^0^ complexes, Pd^0^(NHC)~2~, are efficient catalysts in Heck reactions performed with aryl bromides or chlorides. The Pd^0^(NHC)~2~ that are not stable are generated in situ from Pd^II^ precursors PdY~2~(NHC)~2~ (Y = halides) after a chemical reduction. The latter