𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The Mechanism of the Dötz Reaction: Chromacyclobutenes by Alkyne–Carbene Coupling?

✍ Scribed by Prof. Dr. Peter Hofmann; Dipl.-Chem. Martin Hämmerle

Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
324 KB
Volume
28
Category
Article
ISSN
0044-8249

No coin nor oath required. For personal study only.

✦ Synopsis

5a'e Fig. 3. Measured ESR spectrum of 5 a Table 1. Proton coupling constants u(H) [a] [mT] and g factors of the radical anions of 1-6.

,.e -0.3

📜 SIMILAR VOLUMES

Promotion of the chromium carbene Dötz a
Promotion of the chromium carbene Dötz annulation reaction under sonochemical and dry state adsorption conditions
✍ Joseph P.A. Harrity; William J. Kerr; David Middlemiss 📂 Article 📅 1993 🏛 Elsevier Science 🌐 French ⚖ 766 KB

The chromium cdene D6tx mmlation reaction proweds very rapidly in the presence of uhsomd giving good yields of q~plDdllctan~~vewairup.Moreova,theyieldof~product~been~by~ths~anto silica and heating at mo&mte kmpedum. Boththca~modificationshave~vedtobe~ for a variety of complexes aud allryws.

Steric and electronic limitations for th
Steric and electronic limitations for the Dötz benzannulation of aromatic alkynes
✍ James C. Anderson; John W. Cran; N.Paul King 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 84 KB

As part of an investigation into a new strategy for biaryl synthesis, the Do ¨tz benzannulation of a series of substituted aryl acetylenes was undertaken to determine possible steric and electronic effects exerted by the aryl group. In the ortho position it was found that methyl, methoxy, chloro and